{"id":183248,"date":"2025-10-16T15:38:31","date_gmt":"2025-10-16T13:38:31","guid":{"rendered":"https:\/\/www.ainia.com\/?p=183248"},"modified":"2026-04-10T10:25:15","modified_gmt":"2026-04-10T09:25:15","slug":"caffeine-extraction-from-coffee-supercritical-fluids","status":"publish","type":"post","link":"https:\/\/www.ainia.com\/en\/ainia-news\/caffeine-extraction-from-coffee-supercritical-fluids\/","title":{"rendered":"Caffeine extraction from coffee using supercritical fluids"},"content":{"rendered":"<html><body><div class=\"wpb-content-wrapper\"><p><span data-contrast=\"auto\"><span class=\"TextRun SCXW194446391 BCX8\" lang=\"ES-ES\" xml:lang=\"ES-ES\" data-contrast=\"none\"><span class=\"NormalTextRun SCXW194446391 BCX8\"><span class=\"TextRun SCXW1005685 BCX8\" lang=\"ES-ES\" xml:lang=\"ES-ES\" data-contrast=\"auto\"><span class=\"NormalTextRun SpellingErrorV2Themed SCXW1005685 BCX8\">[vc_row][vc_column][vc_column_text css=\u201d\u201d]<\/span><\/span><\/span><\/span><\/span><strong>Caffeine extraction from coffee<\/strong><span data-contrast=\"auto\"> using supercritical CO\u2082 is one of the most advanced applications of <\/span><a href=\"https:\/\/www.ainia.com\/en\/technological-services\/industrial-production-of-food-ingredients\/\"><strong>supercritical fluid extraction<\/strong><\/a><span data-contrast=\"auto\"><strong> in the food industry.<\/strong> This technique enables the removal of caffeine from raw materials such as green coffee beans or tea leaves, while preserving aromatic compounds and essential oils that contribute to the sensory quality of the final product.<\/span><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"335551550\":1,\"335551620\":1,\"335559738\":240,\"335559739\":240}'>\u00a0<\/span><\/p>\n<p><span data-contrast=\"auto\">In the sections below, we explain what the process involves, the specific conditions under which it is carried out, how supercritical CO\u2082 behaves, and why it has become one of the most widely used <\/span><strong>decaffeination methods<\/strong><span data-contrast=\"auto\"> in the industry.<\/span><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"335551550\":1,\"335551620\":1,\"335559738\":240,\"335559739\":240}'>\u00a0<\/span><\/p>\n<h2 aria-level=\"2\"><b><span data-contrast=\"none\">What is caffeine extraction from coffee with supercritical CO\u2082?<\/span><\/b><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"134245418\":true,\"134245529\":true,\"335551550\":1,\"335551620\":1,\"335559738\":299,\"335559739\":299}'>\u00a0<\/span><\/h2>\n<p><span data-contrast=\"auto\"><strong>Caffeine extraction<\/strong> from coffee using <strong>supercritical CO\u2082<\/strong> relies on the unique properties of carbon dioxide in its supercritical state \u2014 a phase between gas and liquid \u2014 where it flows like a gas but dissolves substances like a liquid.<\/span><br>\n<span data-contrast=\"auto\"> This dual nature makes it an ideal selective solvent for separating caffeine without removing volatile compounds that contribute to flavour and aroma.<\/span><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"335551550\":1,\"335551620\":1,\"335559738\":240,\"335559739\":240}'>\u00a0<\/span><\/p>\n<p><span data-contrast=\"auto\">Thanks to its low toxicity, recyclability, and the absence of chemical residues in the final product, <strong>supercritical CO\u2082<\/strong> has become the cleanest and most effective alternative for producing high-quality decaffeinated coffee and tea.<\/span><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"335551550\":1,\"335551620\":1,\"335559738\":240,\"335559739\":240}'>\u00a0<\/span><\/p>\n<h2 aria-level=\"2\"><b><span data-contrast=\"none\"><img decoding=\"async\" class=\"alignnone size-full wp-image-116346\" src=\"https:\/\/www.ainia.com\/wp-content\/uploads\/2021\/11\/Bloque-4_Altex.jpg\" alt=\"Altex\" width=\"800\" height=\"533\" srcset=\"https:\/\/www.ainia.com\/wp-content\/uploads\/2021\/11\/Bloque-4_Altex.jpg 800w, https:\/\/www.ainia.com\/wp-content\/uploads\/2021\/11\/Bloque-4_Altex-300x200.jpg 300w, https:\/\/www.ainia.com\/wp-content\/uploads\/2021\/11\/Bloque-4_Altex-768x512.jpg 768w\" sizes=\"(max-width: 800px) 100vw, 800px\"><\/span><\/b><\/h2>\n<h2 aria-level=\"2\"><b><span data-contrast=\"none\">Process conditions for caffeine extraction with supercritical CO\u2082<\/span><\/b><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"134245418\":true,\"134245529\":true,\"335551550\":1,\"335551620\":1,\"335559738\":299,\"335559739\":299}'>\u00a0<\/span><\/h2>\n<p><span data-contrast=\"auto\">To maintain CO\u2082 in its supercritical state and optimise <\/span><b><span data-contrast=\"auto\">caffeine extraction from coffee<\/span><\/b><span data-contrast=\"auto\">, specific process conditions must be applied:<\/span><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"335551550\":1,\"335551620\":1,\"335559738\":240,\"335559739\":240}'>\u00a0<\/span><\/p>\n<ul>\n<li aria-setsize=\"-1\" data-leveltext=\"\uf0b7\" data-font=\"Symbol\" data-listid=\"19\" data-list-defn-props='{\"335552541\":1,\"335559683\":0,\"335559684\":-2,\"335559685\":720,\"335559991\":360,\"469769226\":\"Symbol\",\"469769242\":[8226],\"469777803\":\"left\",\"469777804\":\"\uf0b7\",\"469777815\":\"hybridMultilevel\"}' data-aria-posinset=\"1\" data-aria-level=\"1\"><strong>Temperature<\/strong><span data-contrast=\"auto\"><strong>:<\/strong> Between <\/span>40\u202f\u00b0C and 80\u202f\u00b0C, typically around 50\u201360\u202f\u00b0C<span data-contrast=\"auto\">, to ensure caffeine solubility without degrading aromatic compounds.<\/span><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"335551550\":1,\"335551620\":1,\"335559738\":240,\"335559739\":240}'>\u00a0<\/span><\/li>\n<\/ul>\n<ul>\n<li aria-setsize=\"-1\" data-leveltext=\"\uf0b7\" data-font=\"Symbol\" data-listid=\"19\" data-list-defn-props='{\"335552541\":1,\"335559683\":0,\"335559684\":-2,\"335559685\":720,\"335559991\":360,\"469769226\":\"Symbol\",\"469769242\":[8226],\"469777803\":\"left\",\"469777804\":\"\uf0b7\",\"469777815\":\"hybridMultilevel\"}' data-aria-posinset=\"2\" data-aria-level=\"1\"><strong>Pressure<\/strong><span data-contrast=\"auto\"><strong>:<\/strong> Between <\/span>100 and 300 bar<span data-contrast=\"auto\">, depending on the raw material and system design. Higher pressures increase CO\u2082 density and its dissolving power.<\/span><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"335551550\":1,\"335551620\":1,\"335559738\":240,\"335559739\":240}'>\u00a0<\/span><\/li>\n<\/ul>\n<ul>\n<li aria-setsize=\"-1\" data-leveltext=\"\uf0b7\" data-font=\"Symbol\" data-listid=\"19\" data-list-defn-props='{\"335552541\":1,\"335559683\":0,\"335559684\":-2,\"335559685\":720,\"335559991\":360,\"469769226\":\"Symbol\",\"469769242\":[8226],\"469777803\":\"left\",\"469777804\":\"\uf0b7\",\"469777815\":\"hybridMultilevel\"}' data-aria-posinset=\"3\" data-aria-level=\"1\"><strong>Time<\/strong><span data-contrast=\"auto\"><strong>:<\/strong> The extraction process may last several hours, depending on the batch size and the desired degree of decaffeination.<\/span><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"335551550\":1,\"335551620\":1,\"335559738\":240,\"335559739\":240}'>\u00a0<\/span><\/li>\n<\/ul>\n<p><span data-contrast=\"auto\">These conditions enable efficient and highly selective caffeine extraction while preserving the sensory profile of the coffee or tea.<\/span><\/p>\n<h2 aria-level=\"2\"><b><span data-contrast=\"none\">How does supercritical CO\u2082 work in caffeine extraction from coffee?<\/span><\/b><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"134245418\":true,\"134245529\":true,\"335551550\":1,\"335551620\":1,\"335559738\":299,\"335559739\":299}'>\u00a0<\/span><\/h2>\n<p><span data-contrast=\"auto\">From a technical perspective,<a href=\"https:\/\/www.ainia.com\/en\/technological-services\/industrial-production\/altex\/co2-supercritical-extraction-and-separation\/\"> <strong>supercritical CO\u2082<\/strong><\/a> functions as a <\/span>tunable solvent<span data-contrast=\"auto\"><strong>,<\/strong> meaning its properties can be adjusted by controlling temperature and pressure. This makes it possible to precisely regulate its affinity for caffeine:<\/span><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"335551550\":1,\"335551620\":1,\"335559738\":240,\"335559739\":240}'>\u00a0<\/span><\/p>\n<ul>\n<li aria-setsize=\"-1\" data-leveltext=\"\uf0b7\" data-font=\"Symbol\" data-listid=\"20\" data-list-defn-props='{\"335552541\":1,\"335559683\":0,\"335559684\":-2,\"335559685\":720,\"335559991\":360,\"469769226\":\"Symbol\",\"469769242\":[8226],\"469777803\":\"left\",\"469777804\":\"\uf0b7\",\"469777815\":\"hybridMultilevel\"}' data-aria-posinset=\"1\" data-aria-level=\"1\"><span data-contrast=\"auto\">In its supercritical state, CO\u2082 has <\/span><strong>low viscosity and high diffusivity<\/strong><span data-contrast=\"auto\">, allowing it to deeply penetrate the plant matrix.<\/span><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"335551550\":1,\"335551620\":1,\"335559738\":240,\"335559739\":240}'>\u00a0<\/span><\/li>\n<\/ul>\n<ul>\n<li aria-setsize=\"-1\" data-leveltext=\"\uf0b7\" data-font=\"Symbol\" data-listid=\"20\" data-list-defn-props='{\"335552541\":1,\"335559683\":0,\"335559684\":-2,\"335559685\":720,\"335559991\":360,\"469769226\":\"Symbol\",\"469769242\":[8226],\"469777803\":\"left\",\"469777804\":\"\uf0b7\",\"469777815\":\"hybridMultilevel\"}' data-aria-posinset=\"2\" data-aria-level=\"1\"><span data-contrast=\"auto\">Its <\/span><strong>high density<\/strong><span data-contrast=\"auto\">, similar to that of a liquid, gives it strong solvating power for target compounds like caffeine.<\/span><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"335551550\":1,\"335551620\":1,\"335559738\":240,\"335559739\":240}'>\u00a0<\/span><\/li>\n<\/ul>\n<ul>\n<li aria-setsize=\"-1\" data-leveltext=\"\uf0b7\" data-font=\"Symbol\" data-listid=\"20\" data-list-defn-props='{\"335552541\":1,\"335559683\":0,\"335559684\":-2,\"335559685\":720,\"335559991\":360,\"469769226\":\"Symbol\",\"469769242\":[8226],\"469777803\":\"left\",\"469777804\":\"\uf0b7\",\"469777815\":\"hybridMultilevel\"}' data-aria-posinset=\"3\" data-aria-level=\"1\"><span data-contrast=\"auto\">By adjusting pressure (typically between <\/span><b><span data-contrast=\"auto\">150 and 250 bar<\/span><\/b><span data-contrast=\"auto\">), operators can <\/span><strong>modulate its selectivity<\/strong><span data-contrast=\"auto\">, extracting caffeine without removing desirable components such as essential oils or flavour compounds.<\/span><span data-ccp-props='{\"134233117\":false,\"134233118\":false,\"335551550\":1,\"335551620\":1,\"335559738\":240,\"335559739\":240}'>\u00a0<\/span><\/li>\n<\/ul>\n<p><span data-contrast=\"auto\">This behaviour makes supercritical CO\u2082 a powerful and versatile tool for efficient, gentle <\/span><strong>caffeine extraction from coffee.\u00a0<\/strong><\/p>\n<h3><strong><span class=\"TextRun SCXW35527972 BCX8\" lang=\"ES-ES\" xml:lang=\"ES-ES\" data-contrast=\"auto\"><span class=\"NormalTextRun SCXW35527972 BCX8\">Advantages of decaffeination methods using supercritical fluids<\/span><\/span><span class=\"EOP SCXW35527972 BCX8\" data-ccp-props=\"{}\">\u00a0<\/span><\/strong><\/h3>\n<p data-start=\"140\" data-end=\"292\"><strong>Supercritical fluid extraction,<\/strong> and particularly <strong>decaffeination using supercritical CO\u2082<\/strong>, offers significant advantages over traditional methods:<\/p>\n<ul data-start=\"294\" data-end=\"688\">\n<li data-start=\"294\" data-end=\"388\">\n<p data-start=\"296\" data-end=\"388\"><strong>Better preservation of aroma and flavour <\/strong>compared to processes using organic solvents.<\/p>\n<\/li>\n<li data-start=\"389\" data-end=\"490\">\n<p data-start=\"391\" data-end=\"490\"><strong>No toxic residues:<\/strong> CO\u2082 is completely removed from the product during system depressurisation.<\/p>\n<\/li>\n<li data-start=\"491\" data-end=\"590\">\n<p data-start=\"493\" data-end=\"590\"><strong>Sustainability:<\/strong> CO\u2082 can be recycled within the process and does not generate harmful waste.<\/p>\n<\/li>\n<li data-start=\"591\" data-end=\"688\">\n<p data-start=\"593\" data-end=\"688\"><strong>High efficiency and selectivity<\/strong>, especially when process conditions are properly optimised.<\/p>\n<\/li>\n<\/ul>\n<p data-start=\"690\" data-end=\"861\">Thanks to these advantages, <strong data-start=\"718\" data-end=\"764\">caffeine extraction with supercritical CO\u2082<\/strong> is currently the industry\u2019s preferred<strong><a href=\"https:\/\/www.ainia.com\/en\/technological-services\/industrial-production-of-food-ingredients\/\"> method for delivering high-quality decaffeinated products.<\/a><\/strong><\/p>\n<p><img decoding=\"async\" class=\"alignnone size-large wp-image-116338\" src=\"https:\/\/www.ainia.com\/wp-content\/uploads\/2021\/11\/Bloque-2_Altex-683x1024.jpg\" alt=\"Altex\" width=\"683\" height=\"1024\" srcset=\"https:\/\/www.ainia.com\/wp-content\/uploads\/2021\/11\/Bloque-2_Altex-683x1024.jpg 683w, https:\/\/www.ainia.com\/wp-content\/uploads\/2021\/11\/Bloque-2_Altex-200x300.jpg 200w, https:\/\/www.ainia.com\/wp-content\/uploads\/2021\/11\/Bloque-2_Altex-768x1152.jpg 768w, https:\/\/www.ainia.com\/wp-content\/uploads\/2021\/11\/Bloque-2_Altex.jpg 800w\" sizes=\"(max-width: 683px) 100vw, 683px\"><\/p>\n<p><em><strong><span class=\"TextRun SCXW53812257 BCX8\" lang=\"ES-ES\" xml:lang=\"ES-ES\" data-contrast=\"auto\"><span class=\"NormalTextRun SpellingErrorV2Themed SCXW53812257 BCX8\">Funded<\/span><span class=\"NormalTextRun SCXW53812257 BCX8\">\u00a0<\/span><span class=\"NormalTextRun SpellingErrorV2Themed SCXW53812257 BCX8\">by<\/span><span class=\"NormalTextRun SCXW53812257 BCX8\">\u00a0<\/span><span class=\"NormalTextRun SpellingErrorV2Themed 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SpellingErrorV2Themed SCXW53812257 BCX8\">specialized<\/span><span class=\"NormalTextRun SCXW53812257 BCX8\">\u00a0in\u00a0<\/span><span class=\"NormalTextRun SpellingErrorV2Themed SCXW53812257 BCX8\">internationalization<\/span><\/span><\/strong><\/em><\/p>\n<p><img decoding=\"async\" class=\"alignnone size-large wp-image-191112\" src=\"https:\/\/www.ainia.com\/wp-content\/uploads\/2026\/02\/Imagen1-1024x109.png\" alt=\"\" width=\"1024\" height=\"109\" srcset=\"https:\/\/www.ainia.com\/wp-content\/uploads\/2026\/02\/Imagen1-1024x109.png 1024w, https:\/\/www.ainia.com\/wp-content\/uploads\/2026\/02\/Imagen1-300x32.png 300w, https:\/\/www.ainia.com\/wp-content\/uploads\/2026\/02\/Imagen1-768x82.png 768w, https:\/\/www.ainia.com\/wp-content\/uploads\/2026\/02\/Imagen1-1536x164.png 1536w, https:\/\/www.ainia.com\/wp-content\/uploads\/2026\/02\/Imagen1.png 1878w\" sizes=\"(max-width: 1024px) 100vw, 1024px\">[\/vc_column_text][\/vc_column][\/vc_row]<\/p>\n<\/div><\/body><\/html>","protected":false},"excerpt":{"rendered":"<p>[vc_row][vc_column][vc_column_text css=\u201d\u201d]Caffeine extraction from coffee using supercritical CO\u2082 is one of the most advanced applications of supercritical fluid extraction in the food industry. This technique enables the removal of caffeine from raw materials such as green coffee beans or tea leaves, while preserving aromatic compounds and essential oils that contribute to the sensory quality of [&hellip;]<\/p>\n","protected":false},"author":249,"featured_media":183242,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"inline_featured_image":false,"footnotes":""},"categories":[1971],"tags":[],"class_list":["post-183248","post","type-post","status-publish","format-standard","hentry","category-technological-innovation"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.5 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Caffeine extraction from coffee using supercritical fluids<\/title>\n<meta name=\"description\" content=\"Discover caffeine extraction from coffee using supercritical CO\u2082 offers a clean, efficient and selective decaffeination method 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